PA6/3T: Polyamide 6/3T

General Properties

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PA6/3T

Polyamide 6/3T


Polyamide 6/3T belongs to the semi-aromatic amorphous polyamides, made of the monomer trimethyl hexamethylene diamine and terephthalic acid (T represents terephthalic acid). Polyamide 6/3T has a quite irregular structure, strongly decreasing the tendency to crystallize.

Structural Formula


Properties

Glass Transition Temperature145 to 153°C
Melting Temperature-
Melting Enthalpy-
Decomposition Temperature460 to 470°C
Young's Modulus2000 MPa
Coefficient of Linear Thermal Expansion80 *10-6/K
Specific Heat Capacity1.6 J/(g*K)
Thermal Conductivity0.23 W/(m*K)
Density1.12 g/cm³
MorphologyAmorphous thermoplastic
General propertiesHigh mechanical stability. High chemical resistance. Good electrical insulation properties. Low processing shrinkage and tendency to wrap
ProcessingExtrusion, injection molding, blow molding
ApplicationsElectrical engineering/electronics (switch housings, gear wheels, push buttons …). Mechanical and apparatus engineering (valve and control blocks, flow meter ...). Water management and filter technology

NETZSCH Measurement

InstrumentDSC 204 F1 Phoenix®
Sample Mass12.73 mg
Isothermal Phase3 min / 3 min / 5 min
Heating/Colling Rates10 K/min
CrucibleAl, pierced lid
AtmosphereN2 (50 ml/min)

Evaluation

Typically an amorphous polymer, PA6/3T exhibits a glass transition with a midpoint temperature of 142°C (1st heating, blue, midpoint) and 147°C (2nd heating, red, midpoint) which was overlapped by a RelaxationWhen a constant strain is applied to a rubber compound, the force necessary to maintain that strain is not constant but decreases with time; this behavior is known as stress relaxation. The process responsible for stress relaxation can be physical or chemical, and under normal conditions, both will occur at the same time. relaxation peak in the 2nd heating. The step heights (Δcp) of this example were approx. 0.39 J/(g.K) (mean value of both heatings).