methods

Thermomechanical Analysis (TMA) 

For measuring both the thermal and the mechanical properties, a thermomechanical analyzer (TMA) is used. Temperature-dependent dimensional changes in solids, liquids and pastes determine the suitability of an application for a given material or provide information about the composition, structure and conditions of processing.

TMA measures these dimensional changes while allowing the sample to be subjected to an additional mechanical load (DIN 51005, ASTM E 831, ASTM D 696, and ASTM D 3386). This makes it possible to determine the thermal length change (with negligible mechanical load: dilatometry, DIN 51045) as well as the thermomechanical characteristics.

Besides the linear thermal expansion and the coefficient of thermal expansion, TMA can also be used to study Phase TransitionsThe term phase transition (or phase change) is most commonly used to describe transitions between the solid, liquid and gaseous states.phase transition temperatures, SinteringSintering is a production process for forming a mechanically strong body out of a ceramic or metallic powder. sintering temperatures, shrinkage steps, Glass Transition TemperatureThe glass transition is one of the most important properties of amorphous and semi-crystalline materials, e.g., inorganic glasses, amorphous metals, polymers, pharmaceuticals and food ingredients, etc., and describes the temperature region where the mechanical properties of the materials change from hard and brittle to more soft, deformable or rubbery.glass transition temperatures, dilatometric softening points, Volumetric ExpansionThe volume of a gas, solid or liquid changes if the temperature, the pressure or the forces acting on that gas/solid/liquid change. In the case of thermal analysis, we are looking at temperature-dependent changes.volumetric expansion, DensityThe mass density is defined as the ratio between mass and volume. density changes, delamination and SinteringSintering is a production process for forming a mechanically strong body out of a ceramic or metallic powder. sintering kinetics.

Instruments for thermomechanical analysis are applied in all areas from research and development to quality control. Typical domains include plastics and elastomers, thermosets, composite materials, adhesives, films and fibers, ceramics, glass and metals.

Measurement on an epoxy resin with a sample length of 6 mm in expansion mode (fused silica sample holder); 1st and 2nd heating runs at a rate of 2 K/min.