Glossary

Carbon Black 

Temperature and atmosphere (purge gas) affect the mass change results. By changing the atmosphere from, e.g., nitrogen to air during the TGA measurement, separation and quantification of additives, e.g., carbon black, and the bulk polymer can become possible.

TGA analysis graph showing polyethylene (PE) filled with 1.8% carbon black, highlighting mass change and combustion temperature.
Figure 1:TGA measurement of PE filled with carbon black
Comparison of thermal gravimetric analysis (TGA) of four carbon black samples, highlighting combustion behavior at varying temperatures.
Figure 2: Comparison of 4 different carbon black samples (sample mass 1 mg ± 0.05 mg) measured in alumina crucibles at a heating rate of 20 K/min

Figure 2

The surface of the carbon black determines the combustion behavior (in oxygen atmosphere). The larger the surface area, the smaller the particle size, the lower the combustion temperature or the faster the combustion takes place at a defined temperature (see figure 2).

Due to this combustion behavior, it is in many cases possible to distinguish between Added Carbon BlackCarbon black acts as a reinforcing filler in tires and other rubber products. In other materials such as plastics, paints, and inks, carbon black is used as a color pigment or as filler to achieve electric conductivity.added carbon black and Pyrolytic CarbonPyrolytic carbon is carbon which is generated by the pyrolysis of organic matter in an oxygen-free atmosphere. pyrolytic carbon. Therefore, the TGA can be used to determine the carbon black content – even in polymers which form pyrolytic soot.

Comparison of four carbon black samples showing mass changes (%TG) against temperature (°C). Key for combustion analysis.
Figure 2: Comparison of 4 different carbon black samples (sample mass 1 mg ± 0.05 mg) measured in alumina crucibles at a heating rate of 20 K/min
Two professionals analyze charts and data on a table, one using a tablet and the other taking notes, in a bright workspace.

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