Thermoreflectance is a method for determining the Thermal DiffusivityThermal diffusivity (a with the unit mm2/s) is a material-specific property for characterizing unsteady heat conduction. This value describes how quickly a material reacts to a change in temperature.thermal diffusivity and Thermal ConductivityThermal conductivity (λ with the unit W/(m•K)) describes the transport of energy – in the form of heat – through a body of mass as the result of a temperature gradient (see fig. 1). According to the second law of thermodynamics, heat always flows in the direction of the lower temperature.thermal conductivity of thin films with thicknesses in the nanometer range. 

In contrast with the conventional laser flash method, there is no infrared detector used to measure the temperature increase in the sample following a short laser pulse. Instead, the temperature-dependent reflectivity of a surface is used to generate the measurement signal (voltage change).

The thin film is heated by a short laser pulse (pump laser). At the same time, an additional laser (probe laser) is left on continuously. The laser light of the probe laser is reflected by the film surface to the detector. The absolute value of voltage change in the detector is proportional to the temperature change of the film’s surface. A model calculation on the basis of the voltage change (thermogram) yields the thermal diffusion time and thermal diffusivity of thin films.

The thermal diffusion time (t) is dependent on the thickness (d) and thermal diffusivity (a). The possible thermal diffusion time ranges can be seen in figure 1. The lower limit for the LFA 467, for example, is ~500 µs which is comparable to a copper plate with a thickness of 200 µm. In contrast with this, the PicoTR (pico-second thermoreflectance apparatus) is able to measure a molybdenum film with a thickness of 100µm. For applications in the range between the LFA and PicoTR, the more cost-effective NanoTR (nano-second thermoreflectance apparatus) is available.

NETZSCH Thermoreflectance Systems