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Binder Burnout of Stabilized Zirconia

Introduction

Zirconium dioxide (ZrO2) is one of the most often studied ceramic materials. Upon heating, zirconia undergoes disruptive phase changes. By adding small percentages of yttria, these phase changes are eliminated, and the resulting material has superior thermal, mechanical and electrical properties.

NETZSCH STA 449 F5 Jupiter thermal analysis instrument with multiple components for advanced material testing and analysis.
1) STA 449 F5 Jupiter®

Measurement Conditions and Results

This STA measurement between room temperature and 1200°C exhibits two small losses up to 450°C (3.4% in total; green TGA curve) which correspond very well with the two exothermic peaks at 197°C and 399°C in the DSC curve (blue). These effects (mass loss up to 500°C, exothermic peaks with high enthalpies) can be typically observed during the binder burnout of ceramic materials. The small endothermic DSC peak at around 67°C is caused by the melting of the binder.

TGA and DSC curves showing zirconium dioxide thermal analysis, highlighting mass changes at significant temperature points.
2) STA measurement of zirconium dioxide (26.2 mg) in platinum crucibles at a heating rate of 10 K/min
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