18.03.2025 by Aileen Sammler

UV-Curing in Polymers: Insights by Means of Thermal Analysis and Rheology with NETZSCH Instruments

The Role of UV-Curing in Polymers: Why it is Revolutionizing Industries

The Role of UV-Curing in Polymers: Insights by Means of Thermal Analysis and Rheology with NETZSCH Instruments

Ultraviolet (UV) Curing (Crosslinking Reactions)Literally translated, the term “crosslinking“ means “cross networking”. In the chemical context, it is used for reactions in which molecules are linked together by introducing covalent bonds and forming three-dimensional networks.curing has transformed material processing across multiple industries, offering rapid, energy-efficient, and solvent-free polymerization. From high-performance coatings in the automotive sector, durable medical adhesives, and biocompatible dental materials, to high-precision 3D printing resins, UV-curable materials are pushing the boundaries of innovation. Unlike conventional thermal Curing (Crosslinking Reactions)Literally translated, the term “crosslinking“ means “cross networking”. In the chemical context, it is used for reactions in which molecules are linked together by introducing covalent bonds and forming three-dimensional networks.curing, which requires prolonged heating, UV Curing (Crosslinking Reactions)Literally translated, the term “crosslinking“ means “cross networking”. In the chemical context, it is used for reactions in which molecules are linked together by introducing covalent bonds and forming three-dimensional networks.curing enables instant solidification, significantly enhancing production speed and reducing energy consumption.

A major industry shift is the transition from traditional mercury vapor lamps to LED-UV Curing (Crosslinking Reactions)Literally translated, the term “crosslinking“ means “cross networking”. In the chemical context, it is used for reactions in which molecules are linked together by introducing covalent bonds and forming three-dimensional networks.curing systems. LED-UV light offers a longer lifespan, lower energy consumption, and more precise wavelength control, leading to improved Curing (Crosslinking Reactions)Literally translated, the term “crosslinking“ means “cross networking”. In the chemical context, it is used for reactions in which molecules are linked together by introducing covalent bonds and forming three-dimensional networks.curing performance and more sustainable manufacturing processes. However, this shift requires adjustments in material formulations, which can be optimized through precise thermal and rheological analysis.

However, optimizing UV-curable polymer formulations demands in-depth understanding of their thermal behavior, curing kinetics, and rheological properties. Advanced thermal and rheological analysis methods by NETZSCH provide critical insights into these processes, ensuring the reliability and performance of UV-curable materials in real-world applications.

UV Application Examples

Understanding UV-Curing in Polymers

UV-curable polymers rely on photoinitiators, which, when exposed to UV light, generate reactive species that trigger polymerization. This leads to the formation of highly cross-linked structures with superior mechanical and chemical resistance. The key benefits of UV curing include:

  • Instant Curing: Reduces processing time from hours to seconds
  • Lower Energy Demand: Eliminates the need for high-temperature ovens
  • Environmentally Friendly: Solvent-free formulations reduce VOC emissions
  • Precision Control: Localized curing enables high-resolution additive manufacturing


To tailor UV-curable formulations for optimal performance, it is essential to characterize their curing behavior, viscosity evolution, and post-cure mechanical properties using advanced analytical techniques.

Thermal Analysis Techniques by NETZSCH for UV-Curing

The NETZSCH DSC 300 Caliris® with UV option

1. Differential Scanning Calorimetry (DSC)

The NETZSCH DMA 303 Eplexor® comes with UV light exposure for curing reactions.
The DEA 288 Ionic with UV accessory

3. Dielectric Analysis (DEA)

  • Application: Tracks changes in dielectric properties, providing insights into polymerization dynamics.
  • Relevance to UV Curing: DEA enables in-situ real-time curing analysis, detecting the degree of cross-linking and reaction progress.
  • NETZSCH Instrument:DEA 288 Ionic
  • Watch our short webinar to find out more: Episode 23: Study UV cure using DEA

4. Kinetics Modeling with NETZSCH Kinetics Neo

NETZSCHKinetics Neo is an Advanced Software solution that enables precise modeling and simulation of curing kinetics in UV-curable polymers, allowing manufacturers to predict reaction behavior, optimize formulation parameters, and improve process efficiency.

Download your free trial here: Request Demo Version of Kinetics Form - NETZSCH Kinetics Neo

Kinetics Neo is an Advanced Software solution that enables precise modeling and simulation of curing kinetics in UV-curable polymers.
The NETZSCH Kinexus Prime ultra+ rotational rheometer with UV system

5. Rheological Analysis of UV-Curable Polymers

Rotational Rheometry

Conclusion

The ability to accurately characterize UV-curable materials is crucial for advancing applications in additive manufacturing, electronics, medical devices, and high-performance coatings. NETZSCH's state-of-the-art instruments, including DSC 300 Caliris®, DMA 303 Eplexor®, DEA 288 Ionic, and the Kinexus Prime rheometer series, offer unparalleled insights into the curing kinetics, mechanical properties, and rheological behavior of UV-sensitive polymers. By leveraging these analytical tools, manufacturers can enhance material performance, reduce defects, and optimize production processes.

For more insights and application studies, visit our website or contact us directly at any time.

Watch also our webinar interview series about 3D printing myths

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