
18.03.2025 by Aileen Sammler
UV-Curing in Polymers: Insights by Means of Thermal Analysis and Rheology with NETZSCH Instruments
The Role of UV-Curing in Polymers: Why it is Revolutionizing Industries
The Role of UV-Curing in Polymers: Insights by Means of Thermal Analysis and Rheology with NETZSCH Instruments
Ultraviolet (UV) Curing (Crosslinking Reactions)Literally translated, the term “crosslinking“ means “cross networking”. In the chemical context, it is used for reactions in which molecules are linked together by introducing covalent bonds and forming three-dimensional networks.curing has transformed material processing across multiple industries, offering rapid, energy-efficient, and solvent-free polymerization. From high-performance coatings in the automotive sector, durable medical adhesives, and biocompatible dental materials, to high-precision 3D printing resins, UV-curable materials are pushing the boundaries of innovation. Unlike conventional thermal Curing (Crosslinking Reactions)Literally translated, the term “crosslinking“ means “cross networking”. In the chemical context, it is used for reactions in which molecules are linked together by introducing covalent bonds and forming three-dimensional networks.curing, which requires prolonged heating, UV Curing (Crosslinking Reactions)Literally translated, the term “crosslinking“ means “cross networking”. In the chemical context, it is used for reactions in which molecules are linked together by introducing covalent bonds and forming three-dimensional networks.curing enables instant solidification, significantly enhancing production speed and reducing energy consumption.
A major industry shift is the transition from traditional mercury vapor lamps to LED-UV Curing (Crosslinking Reactions)Literally translated, the term “crosslinking“ means “cross networking”. In the chemical context, it is used for reactions in which molecules are linked together by introducing covalent bonds and forming three-dimensional networks.curing systems. LED-UV light offers a longer lifespan, lower energy consumption, and more precise wavelength control, leading to improved Curing (Crosslinking Reactions)Literally translated, the term “crosslinking“ means “cross networking”. In the chemical context, it is used for reactions in which molecules are linked together by introducing covalent bonds and forming three-dimensional networks.curing performance and more sustainable manufacturing processes. However, this shift requires adjustments in material formulations, which can be optimized through precise thermal and rheological analysis.
However, optimizing UV-curable polymer formulations demands in-depth understanding of their thermal behavior, curing kinetics, and rheological properties. Advanced thermal and rheological analysis methods by NETZSCH provide critical insights into these processes, ensuring the reliability and performance of UV-curable materials in real-world applications.



Understanding UV-Curing in Polymers
UV-curable polymers rely on photoinitiators, which, when exposed to UV light, generate reactive species that trigger polymerization. This leads to the formation of highly cross-linked structures with superior mechanical and chemical resistance. The key benefits of UV curing include:
- Instant Curing: Reduces processing time from hours to seconds
- Lower Energy Demand: Eliminates the need for high-temperature ovens
- Environmentally Friendly: Solvent-free formulations reduce VOC emissions
- Precision Control: Localized curing enables high-resolution additive manufacturing
To tailor UV-curable formulations for optimal performance, it is essential to characterize their curing behavior, viscosity evolution, and post-cure mechanical properties using advanced analytical techniques.
Thermal Analysis Techniques by NETZSCH for UV-Curing
1. Differential Scanning Calorimetry (DSC)
- Application: Measures heat flow associated with curing reactions and Phase TransitionsThe term phase transition (or phase change) is most commonly used to describe transitions between the solid, liquid and gaseous states.phase transitions.
- Relevance to UV Curing: Photo-DSC enables real-time monitoring of UV-induced polymerization, helping determine reaction kinetics and total curing enthalpy.
- NETZSCH Instrument:DSC 300 Caliris®
- Read the following application example: Thermal and Rheological Characterization of Nail Gel Curing - NETZSCH Analyzing & Testing
- Watch also our short webinar:Episode 22: Study UV cure using DSC
2. Dynamic Mechanical Analysis (DMA)
- Application: Evaluates the mechanical properties of materials as they undergo StressStress is defined as a level of force applied on a sample with a well-defined cross section. (Stress = force/area). Samples having a circular or rectangular cross section can be compressed or stretched. Elastic materials like rubber can be stretched up to 5 to 10 times their original length.stress and deformation.
- Relevance to UV Curing: Monitors viscoelastic changes during and after UV exposure, assessing cross-linking DensityThe mass density is defined as the ratio between mass and volume. density and mechanical strength development.
- NETZSCH Instrument:DMA 303 Eplexor®
- Read also the following application example: Kinetic Analysis of the Storage Modulus to Predict the Thermal Post-Curing of a UV-Cured Resin System - NETZSCH Analyzing & Testing
3. Dielectric Analysis (DEA)
- Application: Tracks changes in dielectric properties, providing insights into polymerization dynamics.
- Relevance to UV Curing: DEA enables in-situ real-time curing analysis, detecting the degree of cross-linking and reaction progress.
- NETZSCH Instrument:DEA 288 Ionic
- Watch our short webinar to find out more: Episode 23: Study UV cure using DEA
4. Kinetics Modeling with NETZSCH Kinetics Neo
NETZSCHKinetics Neo is an Advanced Software solution that enables precise modeling and simulation of curing kinetics in UV-curable polymers, allowing manufacturers to predict reaction behavior, optimize formulation parameters, and improve process efficiency.
- Application: Predicts curing kinetics and reaction mechanisms based on experimental data.
- Relevance to UV Curing: Enables precise modeling of UV-induced polymerization, allowing for optimization of formulation and process parameters.
- NETZSCH Software:Kinetics Neo
- To find out more, please read the following blog article: Focus on Advanced Kinetic Modeling of Photo-induced Curing with UV Light Intensity - NETZSCH Analyzing & Testing
Download your free trial here: Request Demo Version of Kinetics Form - NETZSCH Kinetics Neo
5. Rheological Analysis of UV-Curable Polymers
Rotational Rheometry
- Application: Measures viscosity and viscoelastic behavior under shear.
- Relevance to UV Curing: Helps optimizing flow properties of UV resins before curing and tracks viscosity and modulus changes during photopolymerization.
- NETZSCH Instrument:Kinexus Prime Rheometer (with UV curing accessory)
- Please read also the following case study about UV-curing of 3D printing resins and adhesives:Determining Cure Profile and Post-Cure Shrinkage of Photo-Polymers Using UV Accessory on a Rotational Rheometer - NETZSCH Analyzing & Testing
Conclusion
The ability to accurately characterize UV-curable materials is crucial for advancing applications in additive manufacturing, electronics, medical devices, and high-performance coatings. NETZSCH's state-of-the-art instruments, including DSC 300 Caliris®, DMA 303 Eplexor®, DEA 288 Ionic, and the Kinexus Prime rheometer series, offer unparalleled insights into the curing kinetics, mechanical properties, and rheological behavior of UV-sensitive polymers. By leveraging these analytical tools, manufacturers can enhance material performance, reduce defects, and optimize production processes.
For more insights and application studies, visit our website or contact us directly at any time.

Watch also our webinar interview series about 3D printing myths
