General Properties
Short Name:
Name:
UF
Urea-Formaldehyde Resin
Urea-formaldehyde resins (UF; U from urea) are condensation products from urea and aldehydes (mainly formaldehyde). Since cross-linking is a polycondensation reaction, pressure-tight crucibles are required.
Structural Formula

Properties
NETZSCH Measurement

Instrument | DSC 204 F1 Phoenix® |
Sample Mass | 24.04 mg |
IsothermalTests at controlled and constant temperature are called isothermal.Isothermal Phase | 8 min |
Heating/Colling Rates | 5 K/min heating 10 K/min cooling |
Crucible | High-pressure steel crucibles, closed |
Atmosphere | N2 (40 ml/min) |
Evaluation
In the 1st heating (blue), a Glass Transition TemperatureThe glass transition is one of the most important properties of amorphous and semi-crystalline materials, e.g., inorganic glasses, amorphous metals, polymers, pharmaceuticals and food ingredients, etc., and describes the temperature region where the mechanical properties of the materials change from hard and brittle to more soft, deformable or rubbery.glass transition occurred at 45°C (midpoint), overlapped by a small endothermal RelaxationWhen a constant strain is applied to a rubber compound, the force necessary to maintain that strain is not constant but decreases with time; this behavior is known as stress relaxation. The process responsible for stress relaxation can be physical or chemical, and under normal conditions, both will occur at the same time. relaxation effect which is followed by a broad ExothermicA sample transition or a reaction is exothermic if heat is generated.exothermal reaction peak due to the Curing (Crosslinking Reactions)Literally translated, the term “crosslinking“ means “cross networking”. In the chemical context, it is used for reactions in which molecules are linked together by introducing covalent bonds and forming three-dimensional networks.curing reaction (peak temperature 128°C, reaction enthalpy 53 J/g). After controlled cooling, only a Glass Transition TemperatureThe glass transition is one of the most important properties of amorphous and semi-crystalline materials, e.g., inorganic glasses, amorphous metals, polymers, pharmaceuticals and food ingredients, etc., and describes the temperature region where the mechanical properties of the materials change from hard and brittle to more soft, deformable or rubbery.glass transition with a midpoint temperature of 104°C and a step height (Δcp) of 0.14 J/(g*K) can be seen in the 2nd heating (red). This Tg is also overlapped by a RelaxationWhen a constant strain is applied to a rubber compound, the force necessary to maintain that strain is not constant but decreases with time; this behavior is known as stress relaxation. The process responsible for stress relaxation can be physical or chemical, and under normal conditions, both will occur at the same time. relaxation effect. By means of TM-DSC (temperature-modulated DSC), it is possible to separate the Glass Transition TemperatureThe glass transition is one of the most important properties of amorphous and semi-crystalline materials, e.g., inorganic glasses, amorphous metals, polymers, pharmaceuticals and food ingredients, etc., and describes the temperature region where the mechanical properties of the materials change from hard and brittle to more soft, deformable or rubbery.glass transition from the RelaxationWhen a constant strain is applied to a rubber compound, the force necessary to maintain that strain is not constant but decreases with time; this behavior is known as stress relaxation. The process responsible for stress relaxation can be physical or chemical, and under normal conditions, both will occur at the same time. relaxation endotherm and the Curing (Crosslinking Reactions)Literally translated, the term “crosslinking“ means “cross networking”. In the chemical context, it is used for reactions in which molecules are linked together by introducing covalent bonds and forming three-dimensional networks.curing exotherm.